Nonquiescent relaxation in entangled polymer liquids after step shear.

نویسندگان

  • Shi-Qing Wang
  • Sham Ravindranath
  • Pouyan Boukany
  • Michael Olechnowicz
  • Roderic P Quirk
  • Adel Halasa
  • Jimmy Mays
چکیده

Large step shear experiments revealed through particle tracking velocimetry that entangled polymeric liquids display either internal macroscopic movements upon shear cessation or rupturelike behavior during shear. Visible inhomogeneous motions were detected in five samples with the number of entanglements per chain ranging from 20 to 130 at amplitudes of step strain as low as 135%.

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عنوان ژورنال:
  • Physical review letters

دوره 97 18  شماره 

صفحات  -

تاریخ انتشار 2006